Synthesis and investigation of functional characteristics of composite materials based on nanoscale hydroxyapatite and synthetic zeolites
S.A. Bibanaeva, E.A. Bogdanova, V.M. Skachkov
Institute of Solid State Chemistry of the Ural Branch of RAS
DOI: 10.26456/pcascnn/2023.15.913
Original article
Abstract: The article discusses the possibility of obtaining composite materials based on nanostructured hydroxyapatite synthesized by precipitation from solution and synthetic zeolites by mechanochemical synthesis. The synthesized samples are certified using modern physico-chemical methods of analysis. The influence of the qualitative and quantitative composition of the composite and the temperature treatment modes on the sintering processes and the strength characteristics of the studied samples is showed. It has been experimentally established that the maximum strength characteristics and constant composition are possessed by a sample based on hydroxyapatite, the content of the reinforcing additive in which is 15 wt.%. It was also found that the hydroxyapatitezeolite composite exhibits sorption properties against heavy metal ions and fluorine ions. The studies carried out allow us to recommend the samples obtained for further research in order to introduce it into medical practice, but also as a sorption material for the extraction of ions from aqueous solutions.
Keywords: hydroxyapatite, synthetic zeolites, composite materials, microhardness, sorption
- Svetlana A. Bibanaeva – Researcher, Laboratories of heterogeneous processes chemistry, Institute of Solid State Chemistry of the Ural Branch of RAS
- Ekaterina A. Bogdanova – Ph. D., Senior Researcher, Laboratories of heterogeneous processes chemistry, Institute of Solid State Chemistry of the Ural Branch of RAS
- Vladimir M. Skachkov – Ph. D., Senior Researcher, Laboratories of heterogeneous processes chemistry, Institute of Solid State Chemistry of the Ural Branch of RAS
Reference:
Bibanaeva, S.A. Synthesis and investigation of functional characteristics of composite materials based on nanoscale hydroxyapatite and synthetic zeolites / S.A. Bibanaeva, E.A. Bogdanova, V.M. Skachkov // Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials. — 2023. — I. 15. — P. 913-923. DOI: 10.26456/pcascnn/2023.15.913. (In Russian).
Full article (in Russian): download PDF file
References:
1. Barinov S.M., Komlev V.S. Biokeramika na osnove fosfatov kal'tsiya [Calcium phosphate bioceramics]. Moscow, Nauka Publ., 2006, 204 p. (In Russian).
2. Kim H-W., Noh Y-J., Koh Y-H. et al. Effect of CaF2 on densification and properties of hydroxyapatite–zirconia composites for biomedical applications, Biomaterials, 2002, vol. 23, issue 20, pp. 4113-4121. DOI: 10.1016/s0142-9612(02)00150-3.
3. Guidara A., Chaari K., Fakhfakh S., Bouaziz J. The effects of MgO, ZrO2 and TiO2 as additives on microstructure and mechanical properties of Al2O3–FAP composite, Materials Chemistry and Physics, 2017, vol. 202, pp. 358-368. DOI: 10.1016/j.matchemphys.2017.09.039.
4. Htun Z.L., Ahmad N., Thant A.A., Noor A.-F.M. Characterization of CaO –ZrO2 reinforced hap biocomposite for strength and toughness improvement, Procedia Chemistry, 2016, vol. 19, pp. 510-516. DOI: 10.1016/j.proche.2016.03.046.
5. Mobasherpour I., Solati Hashjin M., Razavi Toosi S.S., Darvishi Kamachali R. Effect of the addition ZrO2– Al2O3 on nanocrystalline hydroxyapatite bending strength and fracture toughness, Ceramics International, 2009, vol. 35, issue 4, pp. 1569-1574. DOI: 10.1016/j.ceramint.2008.08.017.
6. Bogdanova E.A., Skachkov V.М., Giniyatullin I.M. et al. Poluchenie biokomozitov na osnove nanorazmernogo gidroksiapatita s oksidami tsirkoniya i kremniya [Preparation of biocomposites based on nanoscale hydroxyapatite with zirconium and silicon oxides], Fiziko-khimicheskie aspekty izucheniya klasterov, nanostruktur i nanomaterialov [Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials], 2021, issue 13, pp. 655-663. DOI: 10.26456/pcascnn/2021.13.655. (In Russian).
7. Bogdanova E.A., Skachkov, Nefedova K.V. Poluchenie biokomozitov na osnove nanorazmernogo gidroksiapatita s soedineniyami titana [Preparation of biocomposites based on nanoscale hydroxyapatite with titanium compounds], Fiziko-khimicheskie aspekty izucheniya klasterov, nanostruktur i nanomaterialov [Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials], 2022, issue 14, pp. 521-530. DOI: 10.26456/pcascnn/2022.14.521. (In Russian).
8. Giniyatullin I.M., Bogdanova E.A., Nefedova K.V. Razrabotka kompozitsionnykh materialov na osnove nanorazmernogo gidroksiapatita, uprochnennogo oksidami alyuminiya i tsirkoniya [Development of composite materials based on nanoscale hydroxyapatite reinforced with aluminum and zirconium oxides], Fizikokhimicheskie aspekty izucheniya klasterov, nanostruktur i nanomaterialov [Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials], 2020, issue 12, pp. 571-579. DOI: 10.26456/pcascnn/2020.12.571. (In Russian).
9. Pereverzev D.I.,, Bogdanova E.A., Nefedova K.V. Poluchenie biokompozitov na osnove nanorazmernogo gidroksiapatita, dopirovannogo oksidom tsirkoniya i ftoridom kal'tsiya [Creating biocomposites based on nanosized hydroxyapatite doped with zirconium oxide and calcium fluoride], Fiziko-khimicheskie aspekty izucheniya klasterov, nanostruktur i nanomaterialov [Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials], 2020, issue 12, pp. 697-705. DOI: 10.26456/pcascnn/2020.12.697. (In Russian)ю
10. Bogdanova E.A., Giniyatullin I.М., Pereverzev D.I., Razgulyaeva V.М. Vliyanie armiruyushchikh dobavok na protsessy spekaniya i uprochneniya nanorazmernogo gidroksiapatita [Influence of reinforcement additives on sintering and hardening processes of nanoscale hydroxyapatite], Fiziko-khimicheskie aspekty izucheniya klasterov, nanostruktur i nanomaterialov [Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials], 2019, issue 11, pp. 548-554. DOI: 10.26456/pcascnn/2019.11.548. (In Russian).
11. Sabirzyanov N.A., Bogdanova E.A., Khonina T.G. Sposob polucheniya suspenzii gidroksiapatita [A method of obtaining a suspension of hydroxyapatite]. Patent RF, no. 2406693, 2010. (In Russian).
12. Bibanaeva S.A. Sintez alyumosilikatnykh tseolitov v usloviyakh glinozemnogo proizvodstva [Synthesis of aluminosilicate zeolites in the conditions of alumina production], Fiziko-khimicheskie aspekty izucheniya klasterov, nanostruktur i nanomaterialov [Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials], 2022, issue 14, pp. 747-753. DOI: 10.26456/pcascnn/2022.14.747. (In Russian).
13. Bogdanova E.A., Skachkov V.М., Medyankina I.S. et al. Formation of nanodimensional structures in precipitated hydroxyapatite by fluorine substitution, SN Applied Sciences, 2020, vol. 2, issue 9, art. no. 1565, 7 p. DOI: 10.1007/s42452-020-03388-5.