Calculation of the point defect concentration of the cation sublattice and hydroxyl groups in lithium niobate crystals of different composition
N.A. Teplyakova, N.V. Sidorov, M.N. Palatnikov
Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences»
DOI: 10.26456/pcascnn/2020.12.200
Short communication
Abstract: The IR absorption spectra in the region of stretching vibrations of OH-groups of lithium niobate crystals of stoichiometric and congruent compositions are studied. The results of calculations of the OH-groups concentration, the Li / Nb ratio and the concentration of point defects NbLi and VLi coincide with the literature data. The phase diagram of lithium niobate confirms these results. It is shown that an increase in the number of free protons that contribute to conductivity can lead to reducing the optical damage and higher electrical conductivity and the rate of thermal fixation of holograms.
Keywords: single crystal, lithium niobate, defects, IR absorption spectra, stretching vibrations of OH-group
- Natalya A. Teplyakova – Ph. D., Senior Researcher of Sector of Vibrational Spectroscopy of Materials of Electronic Engineering Laboratory, Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences»
- Nikolay V. Sidorov – Dr. Sc., Professor, Chief Researcher and as Head of Sector of Vibrational Spectroscopy of Materials of Electronic Engineering Laboratory, Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences»
- Mikhail N. Palatnikov – Dr. Sc., Chief Researcher and as Head of Materials of Electronic Engineering Laboratory, Tananaev Institute of Chemistry - Subdivision of the Federal Research Centre «Kola Science Centre of the Russian Academy of Sciences»
Reference:
Teplyakova, N.A. Calculation of the point defect concentration of the cation sublattice and hydroxyl groups in lithium niobate crystals of different composition / N.A. Teplyakova, N.V. Sidorov, M.N. Palatnikov // Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials. — 2020. — I. 12. — P. 200-205. DOI: 10.26456/pcascnn/2020.12.200. (In Russian).
Full article (in Russian): download PDF file
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