Author: norAdmin

S.Yu. Menshikov¹, A.N. Malyshev^1,2, V.S. Kurmacheva¹, S.A. Fedorov^3,1, M.O. Tonkushina², A.A. Ostroushko^2
1 Ural State Mining University
² Ural Federal University
³ Institute of Metallurgy of Ural Branch of RAS

Abstract: The catalytic properties of FeSO₄, nanocluster iron-molybdenum polyoxometalate {Mo₇₂Fe₃₀} and nanoscale metallic silver in the liquid-phase oxidation of the ethylene glycol aqueous solutions by hydrogen peroxide were studied. O-phenylenediamine was added to the reaction mixtures obtained after oxidation to determine the oxidation products containing the aldehyde group. The polyoxometalate {Mo₇₂Fe₃₀} was synthesized by a well-known and widely used in practice two-step method. The colloidal silver solution was obtained using a technique based on the Turkevich method. According to the analysis carried out on a laser particle size analyzer, the majority of the silver particles have a size of about 2 nm. The analysis of unreacted ethylene glycol was carried out by GC-FID. According to the conversion of ethylene glycol, nanoscale metallic silver was found to have the highest activity at approximately the same percentage of catalysts in the initial reaction mixture. At the same time, with the addition of o-phenylenediamine, the presence of compounds with an aldehyde group, whose exit time from the chromatographic column is longer than that of the initial ethylene glycol, was noted among the oxidation products.
Keywords: polyoxometalate, keplerate, FeSO4, nanosized metallic argentum, catalytic properties, oxidation of ethandiole, H2O2

O.N. Musskaya, V.K. Krut’ko, I.E. Glazov, E.N. Krutsko, A.I. Kulak
Institute of General and Inorganic Chemistry of the NAS of Belarus

Abstract: In aqueous solutions of magnesium chloride and sodium dihydrogen phosphate at Mg/P molar ratios of 1,0-1,5 and pH of 5-7 in the presence of gallic acid, crystalline hydrates of magnesium hydrophosphate (newberyte – MgHPO₄ꞏ3H₂O) and orthophosphate (Mg₃(PO₄)₂ꞏ22H₂O) were obtained, which after heating at 800°C transformed into pyrophosphates (Mg₂P₂O₇). X-ray phase and thermal analysis methods, as well as infared spectroscopy, showed that the presence of an organic additive in the liquid-phase synthesis of magnesium phosphates does not lead to a noticeable change in the phase composition of the reaction products. It was revealed that gallic acid affects the formation of the structure of crystalline hydrates depending on the Mg/P molar ratio. It was found that with prolonged maturation of the sediments (over 6 months), the size of the unit cell of magnesium phosphates decreases. The obtained magnesium phosphate powders modified with gallic acid exhibit redox activity and are promising for use in biomaterials as resorbable components with antioxidant properties.
Keywords: magnesium phosphates, newberite, magnesium pyrophosphate, gallic acid, liquid phase synthesis, redox activity, polyphenolic compounds

A.A. Nagdalian, P.S. Leontiev, A.B. Golik, A.S. Askerova, A.M. Serov, A.V. Tatov
North Caucasus Federal University

Abstract: In this work, samples of mixed nanoscale iron oxide stabilized with amylopectin were obtained by chemical precipitation in an aqueous medium. This compound has a wide range of applications in biomedical technologies, energy storage and conversion devices due to its supermagnetic properties. The microstructure was studied by scanning electron microscopy and the phase composition by diffractometric method, as well as by computer quantum chemical modeling of the interaction of amylopectin and mixed nanoscale iron oxide. During the study of the phase composition, it was found that the sample is a mixed iron oxide Fe₃O₄ with a cubic face-centered lattice and a spatial group Fd3m. Based on the analysis of the microstructure, it was found that the sample is formed from particles with a diameter of 24 to 54 nm.As a result of computer quantum chemical modeling, it was found that the interaction of iron oxide nanoparticles with amylopectin is energetically advantageous and chemically stable. The most likely interaction is through a hydroxyl group attached to the C₂ first A-bound glucopyranose residue, since optimal values of total energy (E = -3839.330 kcal/mol) and chemical hardness (η = 0.159 eV) are observed during this interaction.
Keywords: nanoparticles, co-deposition method, iron (III) oxide, scanning electron microscopy, stabilizer

Yu.V. Rekh¹, S.A. Bibanaeva², M.S. Valova¹, V.M. Skachkov², O.V. Fedorova¹, N.A. Sabirzyanov^2
1 I.Ya. Postovsky Institute of Organic Synthesis of the Ural Branch of RAS
² Institute of Solid State Chemistry of the Ural Branch of RAS

Abstract: It is shown that the sorption of lanthanum cations by synthetic aluminosilicate zeolite, unlike natural ones, increases both in acidic and neutral conditions by 4 times (from 8 to 26%) and 8 times (from 4 to 33%), and the sorption capacity increases by 3-8 times to 145 and 184 mg/g, respectively. A comparative analysis of the applicability of the adsorption of Langmuir, Freundlich, Temkin, Dubinin-Radushkevich models to describe experimental isotherms of adsorption of lanthanum cations on synthetic zeolite is made. It is shown that the Langmuir model is best suited in aqueous media (R² = 0,9996). This indicates that a homogeneous monolayer surface is formed as a result of sorption. Based on the pseudo-first, pseudo-second order models and the intraparticle diffusion model, an assumption is made about the ion-exchange nature of sorption. It has been shown that zeolites can almost quantitatively extract La³⁺ cations from aqueous solutions and are of interest as sorbents with a high sorption capacity.
Keywords: sorption, purification, sorption activity, synthetic zeolite, aluminosilicate, lanthanum, Langmuir model

D.S. Ryashentsev, M.E. Belenkov, L.Y. Kovalenko
Chelyabinsk State University

Abstract: Using the density functional theory method, geometric optimization of layered polymorphic varieties of boron nitride, in which atoms are located in three different structural positions, was carried out and their energy and electronic properties were determined. The structures of the new polymorphs consist of boron and nitrogen atoms in a sp²-hybridized state and were modeled from hexagonal boron nitride by introducing topological defects 4-6-8, 4-6-10, 4-8-10, 4-16 and 4-6-12. As a result of the analysis, the possibility of the existence of nine new structural varieties was established. However, during the geometric optimization process, three structures turned out to be unstable, which were transformed into more stable polymorphic varieties BN-L_4-8 and BN-L_4-6-8. The layer density of the considered polymorphic varieties varies from 0.651 to 0.727 g/cm².The sublimation energy values of the new structures range from 16,93 to 17,69 eV/(BN). The band gap varies from 3,20 to 4,03 eV. The relationships between the energy and structural parameters are determined.
Keywords: boron nitride, two-dimensional materials, polymorphism, ab initio calculations, crystal structure, band structure

K.I. Sabanin¹, V.M. Skachkov², I.S. Medyankina², E.A. Bogdanova^2,3, N.A. Sabirzyanov^2
1 Ural Federal University named after the first President of Russia B.N. Yeltsin
² Institute of Solid State Chemistry of the Ural Branch of RAS
³ JSC Giredme

Abstract: The article discusses the possibility of dispersion strengthening of nanostructured hydroxyapatite synthesized by precipitation from solution introducing reinforcing additives of non-stoichiometric titanium oxide and zirconium dioxide. The reinforced composite material: hydroxyapatite – non-stoichiometric titanium oxide – zirconium dioxide was obtained by mechanochemical synthesis of hydroxyapatite with doping components followed by annealing at 1000°C. The initial components and synthesized samples were certified using modern physicochemical methods of analysis: X-ray phase analysis, differential thermal analysis, scanning electron microscopy, surface area and porosity analysis, dispersion analysis. The influence of the qualitative and quantitative composition of the composite on the sintering processes and strength characteristics of the studied samples in a wide temperature range of 25-1200°C is shown. It has been experimentally established that the most promising system for developing biocomposites based on it ishydroxyapatite – 15% non-stoichiometric titanium oxide – 5% zirconium dioxide. Composite materials of this composition have a dense, uniform, strong structure with a high degree of crystallinity and a developed surface. They seem to be promising materials for further research with the aim of introducing it into medical practice.
Keywords: hydroxyapatite, titanium oxide, zirconium oxide, sintering, composite biomaterials, microhardness

M.Sh. Sattorov¹, Y.M. Spivak¹, Y.M. Kotcur², A. Kuznetsov³, E.V. Flisyuk², V.A. Moshnikov^1
1 St. Petersburg Electrotechnical University «LETI»
² St. Petersburg State Chemical and Pharmaceutical University
³ Moscow Institute of Physics and Technology (National Research University)

Abstract: Using electrochemical anodic etching, porous silicon layers were formed with subsequent production of nanoparticles. The study of the nature of interaction of porous silicon nanoparticles with a new promising 4,4′-(propanediamido) sodium dibenzoate (malobene) substance was performed using infrared and Raman spectroscopy. It was revealed that during the incorporation process, an interaction occurs between the nanoparticle and maloben, during which the degree of influence of porous Si particles during joint scattering of light decreases, and the vibrational modes of the sodium 4,4′-(propanediamido) dibenzoate molecule become more intense. Characteristic absorption bands associated with the formation of chemical bonds by wave and Raman numbers were detected, and an interpretation of the obtained results from the point of view of the formation of the finished substance was proposed.
Keywords: porous silicon, nanostructured layer, nanoparticles, maloben, chemical bonds, infrared Fourier spectroscopy, Raman spectroscopy, scanning electron microscopy

V.M. Skachkov¹, E.A. Bogdanova^1,2, S.A. Bibanaeva¹, A.G. Shirokova^1
1 Institute of Solid State Chemistry of the Ural Branch of RAS
² JSC Giredmet

Abstract: The hardened composite material with a porous structure was obtained by mechanochemical synthesis of nanostructured hydroxyapatite synthesized by precipitation from an aqueous solution with reinforcing additives of zirconium dioxide and silicic acid. Food gelatin is used as a binder. The influence of the phase composition on physico-chemical properties of coatings (adhesive strength, microhardness, specific surface area, microstructure) is estimated. It has been established that the use of composite material together with gelatin as a part of a bioactive coating makes it possible to increase its hardness and adhesive strength. A patent application has been filed for the developed bioactive coatings based on nanoscale hydroxyapatite and biogenic elements with a binding agent. The composition of the dry mixture based on hydroxyapatite has been developed, which ensures a long shelf life without negative consequences and creates simple transportation conditions. Dilution of the dry mixture with distilled water gives a suspension that is convenient to use for coating implants of any configuration.
Keywords: hydroxyapatite, composite materials, aluminosilicate zeolites, gelatin, collagen, biomaterial, bioactive coatings, adhesion

V.E. Suprunchuk, A.A. Kravtsov, L.V. Tarala, E.V. Medyanik, F.F. Malyavin, V.A. Lapin, D.P. Bedrakov
North-Caucasus Federal University

Abstract: In the course of the work, samples of ceramic powders of yttrium-aluminum garnet doped with ruthenium ions were obtained. The introduced amount of ruthenium was 5 and 10 wt.%, respectively. The annealing temperatures were 1150 and 1600°C. In the course of the work, changes in the morphology of ceramic powders of yttrium-aluminum garnet doped with ruthenium ions were considered using scanning electron microscopy. The elemental composition was studied using energy-dispersive spectroscopy. The phase composition was investigated by X-ray phase analysis. The specific surface area of the ceramic powder was estimated using the Brunauer-Emmett-Teller method. For the obtained samples, an increase in the specific surface area of the ceramic powder with a decrease in the quantitative content of ruthenium in the system was revealed. The presence of impurity phases was established for all samples. It was found that increasing the calcination temperature to 1600°C led to a decrease in the quantitative content of impurity phases, but did not lead to their complete elimination. The sample with the closest to a single-phase composition was obtained with a ruthenium content of no more than 5 wt.% in the material. The results obtained using differential thermal analysis showed that the ruthenium content in the amounts used does not affect the kinetics of phase transitions, as well as the kinetics of mass loss of the precursor powders.
Keywords: yttrium aluminum garnet, alloying, ceramic powder, differential thermal analysis, ruthenium