Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials
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Investigation of the process of polymer stabilization of mixed iron oxide with amylopectin

A.A. Nagdalian, P.S. Leontiev, A.B. Golik, A.S. Askerova, A.M. Serov, A.V. Tatov

North Caucasus Federal University

DOI: 10.26456/pcascnn/2024.16.951

Original article

Abstract: In this work, samples of mixed nanoscale iron oxide stabilized with amylopectin were obtained by chemical precipitation in an aqueous medium. This compound has a wide range of applications in biomedical technologies, energy storage and conversion devices due to its supermagnetic properties. The microstructure was studied by scanning electron microscopy and the phase composition by diffractometric method, as well as by computer quantum chemical modeling of the interaction of amylopectin and mixed nanoscale iron oxide. During the study of the phase composition, it was found that the sample is a mixed iron oxide Fe3O4 with a cubic face-centered lattice and a spatial group Fd3m. Based on the analysis of the microstructure, it was found that the sample is formed from particles with a diameter of 24 to 54 nm.As a result of computer quantum chemical modeling, it was found that the interaction of iron oxide nanoparticles with amylopectin is energetically advantageous and chemically stable. The most likely interaction is through a hydroxyl group attached to the C2 first A-bound glucopyranose residue, since optimal values of total energy (E = -3839.330 kcal/mol) and chemical hardness (η = 0.159 eV) are observed during this interaction.

Keywords: nanoparticles, co-deposition method, iron (III) oxide, scanning electron microscopy, stabilizer

  • Andrey A. Nagdalian – Ph. D., Senior Researcher, Research Laboratory of Food and Industrial Biotechnology, Faculty of Food Engineering and Biotechnology named after Academician A.G. Khramtsov, North Caucasus Federal University
  • Pavel S. Leontiev – 3rd year student, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University
  • Alexey B. Golik – Assistant, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University
  • Alina S. Askerova – 2nd year student, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University
  • Alexander M. Serov – 1st year student, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University
  • Alexey V. Tatov – 1st year student, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University

Reference:

Nagdalian, A.A. Investigation of the process of polymer stabilization of mixed iron oxide with amylopectin / A.A. Nagdalian, P.S. Leontiev, A.B. Golik, A.S. Askerova, A.M. Serov, A.V. Tatov // Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials. — 2024. — I. 16. — P. 951-959. DOI: 10.26456/pcascnn/2024.16.951. (In Russian).

Full article (in Russian): download PDF file

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