Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials
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Metal membranes for hydrogen purification: problems, trends and prospects of application

V.A. Polukhin, S.Kh. Estemirova

Institute of Metallurgy of the Ural Branch of the RAS

DOI: 10.26456/pcascnn/2024.16.686

Review

Abstract: The problems associated with the global warming due to greenhouse gas emissions from human activities are driving the search for new technologies to reduce CO2 emissions from the fossil fuel combustion. Hydrogen is a clean and efficient energy carrier, so the hydrogen energy is considered as one of the strategic directions for the development of the energy security and sustainability. Although hydrogen can be produced by electrolysis of water, most of the hydrogen produced worldwide currently comes from steam reforming of natural gas, which must be purified to ultra-high purity for economic reasons. Traditional methods based on pressure swing absorption-desorption using cryogenic distillation are energy intensive, which motivates the development of new highly selective and energy efficient H2 purification technologies. Such technologies include rapidly developing membrane technology, which at the moment has not yet reached the level required for its widespread industrial application. In this review article, we analyze the main aspects of current research in the field of hydrogen purification technology using dense metal membranes, with an emphasis on their technological stability due to the selection of their chemical composition (including multicomponent) and optimization of the structural state. We also considered the prospects for further development and use of this technology for economic needs.

Keywords: membrane gas separation, hydrogen purification, BCC structure, FCC structure, high- entropy alloys, amorphous alloys, solubility, hydrogen permeability, diffusion, thermal stability, brittleness

  • Valery A. Polukhin – Dr. Sc., Chief Researcher, Institute of Metallurgy of the Ural Branch of the RAS
  • Svetlana Kh. Estemirova – Ph. D. Senior Researcher, Institute of Metallurgy of the Ural Branch of the RAS

Reference:

Polukhin, V.A. Metal membranes for hydrogen purification: problems, trends and prospects of application / V.A. Polukhin, S.Kh. Estemirova // Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials. — 2024. — I. 16. — P. 686-710. DOI: 10.26456/pcascnn/2024.16.686. (In Russian).

Full article (in Russian): download PDF file

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