Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials
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Nanostructured catalysts of the turpentine emulsion polymerization under the influence of potassium persulphate

A.A. Ostroushko1, S.Yu.. Menshikov2, D.A. Rozhentsev3, N.K. Tkachev3, A.Ya.. Golub1, M.O. Tonkushina1

1 Ural Federal University named after the first President of Russia B.N. Yeltsin
2 Ural State Mining University
3 The Institute of High Temperature Electrochemistry of the Ural Branch of the Russian Academy of Sciences

DOI: 10.26456/pcascnn/2022.14.829

Original article

Abstract: We have revealed the catalytic activity for initiating the water-emulsion turpentine polymerization of some nanostructured materials such as Keplerate type Mo72Fe30 nanocluster polyoxometalate, nanoporous iron and nanoporous composite of intermetallic compounds Pd2In@Pd3In obtained by dealloying of equiatomic alloys Fe – Mn and Pd – In. For polyoxometalate solutions and nanoporous metal samples, respectively, the yield of sufficiently pure polyterpene resins when using the potassium persulphate initiation depends on the nature of the contact between the catalysts and substrates: solid-liquid-liquid or liquid-liquid. A system that did not contain catalysts was taken as the reaction medium for comparison. Based on the obtained data on the softening point, the molecular weight of the resin samples was determined. Infrared spectroscopy was used to identify the obtained products. In the reaction medium (mainly aqueous) after the isolation of polyterpene resins, chromatographic analysis revealed so valuable products as alpha-terpineol, which is used as an intermediate for obtaining flavors and flotation agents.

Keywords: Nanostructured initiation catalysts, polyoxometalates, metals, emulsion polymerization, turpentine, polyterpene resins, potassium persulfate

  • Alexander A. Ostroushko – Dr. Sc., Professor, Chief Researcher, Head of Department of Chemical Materials Science, Ural Federal University named after the first President of Russia B.N. Yeltsin
  • Sergei Yu.. Menshikov – Ph. D., Docent, Chemistry Department, Ural State Mining University
  • Danil A. Rozhentsev – Junior Researcher, The Institute of High Temperature Electrochemistry of the Ural Branch of the Russian Academy of Sciences
  • Nikolai K. Tkachev – Dr. Sc., Chief Researcher, Molten Salts Laboratory, The Institute of High Temperature Electrochemistry of the Ural Branch of the Russian Academy of Sciences
  • Alexey Ya.. Golub – Assistant, Department of Analytical Chemistry and Environmental Chemistry, Institute of Natural Sciences and Mathematics, Ural Federal University named after the first President of Russia B.N. Yeltsin
  • Margarita O. Tonkushina – Ph. D., Researcher, Department of Chemical Materials Science, Institute of Natural Sciences and Mathematics, Ural Federal University named after the first President of Russia B.N. Yeltsin

Reference:

Ostroushko, A.A. Nanostructured catalysts of the turpentine emulsion polymerization under the influence of potassium persulphate / A.A. Ostroushko, S.Yu.. Menshikov, D.A. Rozhentsev, N.K. Tkachev, A.Ya.. Golub, M.O. Tonkushina // Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials. — 2022. — I. 14. — P. 829-837. DOI: 10.26456/pcascnn/2022.14.829. (In Russian).

Full article (in Russian): download PDF file

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