Study of the structure and properties of zinc silicate stabilized with L-histidine
A.A. Blinova1, M.A. Yasnaya1, D.G. Maglakelidze1, M.A. Taravanov1, V.A. Lapin1,2, P.S. Leontiev1
1 North Caucasus Federal University
2 Federal Research Centre The Southern Scientific Centre of The Russian Academy of Sciences
DOI: 10.26456/pcascnn/2022.14.763
Original article
Abstract: This paper presents the results of a study of the process of stabilization of zinc silicate nanoparticles using the amino acid L-histidine. Zinc acetate was used as a precursor, sodium silicate was used as a precipitant, and the amino acid L -histidine acted as a stabilizer. Synthesis was carried out by chemical precipitation in an aqueous medium. A simultaneous thermal analysis was carried out, as a result of which it was found that the addition of an amino acid to nanosized zinc silicate has a great influence on the crystal structure and thermal transitions for this material. Next, the X-ray phase analysis was carried out, which showed that of zinc silicate particles have an amorphous structure and are in a nanoscale state. At the next stage of the work, the process of interaction of an amino acid with a zinc silicate particle was studied by IR spectroscopy. The results of the study showed that stabilization of particles is accompanied by the formation of a chemical bond between silicon in the zinc silicate molecule and the amino group in the L -histidine molecule.
Keywords: nanosized zinc silicate, amino acids, L-histidine, zinc acetate, sodium silicate, phase composition, simultaneous thermal analysis, derivatogram, IR spectroscopy, powder diffractometry
- Anastasiya A. Blinova – Ph. D., Assistant professor, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University
- Mariya A. Yasnaya – Ph. D., Assistant professor, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University
- David G. Maglakelidze – 4nd year student, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University
- Maxim A. Taravanov – 2nd year student, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University
- Vyacheslav A. Lapin – Researcher of the Research Laboratory of Physical and Chemical Methods of Analysis, North Caucasus Federal University, Ph. D., Researcher, Laboratory of Physics and Technology of Semiconductor Nanoheterostructures for Microwave Electronics and Photonic Federal Research Centre The Southern Scientific Centre of The Russian Academy of Sciences
- Pavel S. Leontiev – 2nd year student, Department of Physics and Technology of Nanostructures and Materials, Faculty of Physics and Technology, North Caucasus Federal University
Reference:
Blinova, A.A. Study of the structure and properties of zinc silicate stabilized with L-histidine / A.A. Blinova, M.A. Yasnaya, D.G. Maglakelidze, M.A. Taravanov, V.A. Lapin, P.S. Leontiev // Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials. — 2022. — I. 14. — P. 763-770. DOI: 10.26456/pcascnn/2022.14.763. (In Russian).
Full article (in Russian): download PDF file
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