Equilibrium phase composition and mutual solubilities in fractal nanoparticles of the W – Cr heavy pseudo-alloy
A.V. Shishulin1, A.V. Shishulina2,3
1G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Nizhny Novgorod, Russia
2R.E. Alekseev Nizhny Novgorod State Technical University, Dzerzhinsk, Russia
3N.I. Lobachevsky National Research Nizhny Novgorod State University, Nizhny Novgorod, Russia
Abstract: The influence of the nanomorphology on phase equilibria in core-shell nanoparticles of the stratifying W – Cr solid solutions has been simulated using methods of the equilibrium chemical thermodynamics. The nanoparticle shape has been determined by the value of the fractal dimension. The dependences of the mutual solubilities on the fractal dimension of nanoparticles have been calculated and some significant changes in the thermal stability of heterogeneous states in nanoparticles of different shapes have been revealed.
Keywords: decomposition of solid solutions, solubility, shape effect, core-shell, tungsten, chromium, fractal dimension.
Shishulin, A.V. Equilibrium phase composition and mutual solubilities in fractal nanoparticles of the W – Cr heavy pseudo-alloy / A.V. Shishulin, A.V. Shishulina // Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials: Interuniversity collection of proceedings / Ed. by V.M. Samsonov, N.Yu. Sdobnyakov. – Tver: TSU, 2019. – I. 11. – P. 380-388.
Full text (in Russian): download PDF file