Several peculiarities of high-temperature phase equilibria in nanoparticles of the Six – Ge1-x system
A.V. Shishulin1, A.V. Shishulina2,3
1G.A. Razuvaev institute of organometallic chemistry of Russian Academy of Sciences, Nizhny Novgorod, Russia
2R.E. Alekseev Nizhny Novgorod State Technical University, Dzerzhinsk, Russia
3N.I. Lobachevsky National Research Nizhny Novgorod State University, Nizhny Novgorod, Russia
Abstract: Phase equilibria in Six – Ge1-x nanoparticles of various compositions within the two-phase region between the liquidus and solidus temperatures have been simulated by using methods of the equilibrium chemical thermodynamics. It has been shown that the equilibrium compositions of liquid and solid phases dramatically depend on the initial composition of a nanoparticle and the character of such dependences is different at different temperatures. Reducing the size of a nanoparticle is accompanied by narrowing the temperature interval of the two-phase region.
Keywords: nanostructuring, nanoparticles, germanium, silicon, melting, liquidus, solidus.
Shishulin, A.V. Several peculiarities of high-temperature phase equilibria in nanoparticles of the Six – Ge1-x system / A.V. Shishulin, A.V. Shishulina // Physical and chemical aspects of the study of clusters, nanostructures and nanomaterials: Interuniversity collection of proceedings / Ed. by V.M. Samsonov, N.Yu. Sdobnyakov. – Tver: TSU, 2019. – I. 11. – P. 268-276.
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